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21.
The electrochemical determinations of 4-chlorophenol (4-CP) and 4-nitrophenol (4-NP) by chronoamperometry (CA) and multiple pulsed amperometry (MPA) using expanded graphite-epoxy composite (EG-Epoxy) and rotating spectral graphite disc (SG) electrodes are reported. The electrochemical behaviours of both electrodes in the presence of organics informed about oxidation peak potential and the electrode fouling with organics concentration increasing. Setting up the oxidation peak potential as detection potential, only SG gave good electroanalytical performance using CA. However, by MPA applying both electrodes exhibited the capability to assess electrochemically and quantitatively the pollutants from aqueous solutions. UV spectrometric method detecting 4-CP and 4-NP at λ = 280 nm and λ = 398 nm wavelength, respectively was used for validation and parallel determinations. 相似文献
22.
Simultaneous electrochemical determination of nitrate and nitrite in aqueous solution using Ag-doped zeolite-expanded graphite-epoxy electrode 总被引:2,自引:0,他引:2
In this work a new electrochemical sensor based on an Ag-doped zeolite-expanded graphite-epoxy composite electrode (AgZEGE) was evaluated as a novel alternative for the simultaneous quantitative determination of nitrate and nitrite in aqueous solutions. Cyclic voltammetry was used to characterize the electrochemical behavior of the electrode in the presence of individual or mixtures of nitrate and nitrite anions in 0.1 M Na2SO4 supporting electrolyte. Linear dependences of current versus nitrate and nitrite concentrations were obtained for the concentration ranges of 1-10 mM for nitrate and 0.1-1 mM for nitrite using cyclic voltammetry (CV), chronoamperometry (CA), and multiple-pulsed amperometry (MPA) procedures. The comparative assessment of the electrochemical behavior of the individual anions and mixtures of anions on this modified electrode allowed determining the working conditions for the simultaneous detection of the nitrite and nitrate anions. Applying MPA allowed enhancement of the sensitivity for direct and indirect nitrate detection and also for nitrite detection. The proposed sensor was applied in tap water samples spiked with known nitrate and nitrite concentrations and the results were in agreement with those obtained by a comparative spectrophotometric method. This work demonstrates that using multiple-pulse amperometry with the Ag-doped zeolite-expanded graphite-epoxy composite electrode provides a real opportunity for the simultaneous detection of nitrite and nitrate in aqueous solutions. 相似文献
23.
Vasile Georgescu Gianina Dobrescu Florica Papa Niculae I. Ionescu 《Reaction Kinetics and Catalysis Letters》2008,94(2):345-350
Benzene total oxidation on a Cu-Cr supported catalyst was investigated using the work function method. Above 300°C, the majority
of the oxygen species on the surface was O2− in the absence or in the presence of hydrocarbon. 相似文献
24.
Florica Papa Catalin Negrila Gianina Dobrescu Akane Miyazaki Ioan Balint 《天然气化学杂志》2011,20(5):537-542
Fine and well dispersed Pt-Cu bimetallic nanoparticles stabilized by polyvinyl pyrrolidone (PVP) were synthesized by alkaline polyol method. The molar ratio of Pt to Cu was 1 : 1. Further, the Pt-Cu bimetallic nanoparticles were supported on alumina and their catalytic behavior in methane combustion was investigated. The as-prepared as well as the supported Pt-Cu nanoparticles were characterized by transmission elec-tron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), fractal analysis and X-ray diffraction (XRD). The dependence of methane combustion on the morphology and surface composition of Pt-Cu nanoparticles was analyzed based on the experimental results. 相似文献
25.
Florica Adriana Jerca Valentin Victor Jerca Richard Hoogenboom 《Journal of polymer science. Part A, Polymer chemistry》2019,57(3):360-366
Thermoresponsive polymers that undergo a solubility phase transition in water are important as basis for the development for a wide variety of responsive and smart materials. In this study, the synthesis of thermoresponsive copolymers is demonstrated by the straightforward one‐pot statistical postpolymerization modification of well‐defined poly(2‐isopropenyl‐2‐oxazoline) (PiPOx) by ring‐opening reaction with multiple carboxylic acids. The reactions are carried out using dual, triple, and quadruple mixtures of up to four different aliphatic carboxylic acids. The cloud point temperatures of the resulting polymethacrylamide copolymers with ester pendent groups can be finely tuned by adjusting the feed ratio and the hydrophilic–hydrophobic balance of the acids that are used for the ring‐opening modification of PiPOx. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 360–366 相似文献
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27.
We classify all the possible asymptotic behavior at the origin for positive solutions of quasilinear elliptic equations of the form div(|∇u|p−2∇u)=b(x)h(u) in Ω?{0}, where 1<p?N and Ω is an open subset of RN with 0∈Ω. Our main result provides a sharp extension of a well-known theorem of Friedman and Véron for h(u)=uq and b(x)≡1, and a recent result of the authors for p=2 and b(x)≡1. We assume that the function h is regularly varying at ∞ with index q (that is, limt→∞h(λt)/h(t)=λq for every λ>0) and the weight function b(x) behaves near the origin as a function b0(|x|) varying regularly at zero with index θ greater than −p. This condition includes b(x)=θ|x| and some of its perturbations, for instance, b(x)=θ|x|m(−log|x|) for any m∈R. Our approach makes use of the theory of regular variation and a new perturbation method for constructing sub- and super-solutions. 相似文献
28.
C. Doroftei E. Rezlescu P. Dorin Popa N. Rezlescu 《Crystal Research and Technology》2006,41(11):1112-1119
Rare‐earth substituted strontium ferrite nanopowders SrFe12‐xRxO19 (R = La, Gd and Er; x = 0.2, 0.5 and 1) were prepared by sol‐gel‐autocombustion method and subsequent heat treatments. Structural and magnetic properties of SrFe12‐xRxO19 powders heat treated at 800, 900 and 10000C, for various times, were characterized with an X‐ray diffractometer, a vibrating sample magnetometer and a scanning electron microscope. The results of X‐ray diffraction measurements showed the M‐type hexagonal structure formation by heat treatments. Magnetic properties, such as specific saturation magnetization σs, specific remanent magnetization σr and coercivity Hc, as well as microstructure depend on the heat treatment conditions (temperature and time). The coercivity Hc exhibits a great increase after a critical heat treatment time. When the heat treatment time increases, one obtains an increase in Hc after a shorter heat treatment time. This jump of Hc was explained by a transition from the superparamagnetic state to normal state of the single domain nanoparticles. The occurrence of an agglomerated structure composed of magnetically interacting ultrafine crystallites also contributes to the increase of Hc.The heat treatment determines a reduced grain growth due to the internal stress generated by R ions. With increasing R content the σs and σr decrease due to the dissolution of R ions into the hexaferrite lattice. We believe that by selecting the time and temperature of the heat treatment, microstructure and magnetic properties suitable for magnetic recording media application can be obtained. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
29.
Adelina Udrescu Stefania Florica Madalina Chivu Ionel Mercioniu Elena Matei Mihaela Baibarac 《Molecules (Basel, Switzerland)》2021,26(23)
In this work, new results concerning the potential of mixtures based on nitrogen doped titanium dioxide (TiO2:N) and carbon nanotubes (CNTs) as possible catalyst candidates for the rhodamine B (RhB) UV photodegradation are reported. The RhB photodegradation was evaluated by UV–VIS absorption spectroscopy using samples of TiO2:N and CNTs of the type of single-walled carbon nanotubes (SWNTs), double-wall carbon nanotubes (DWNTs), multi-wall carbon nanotubes (MWNTs), and single-walled carbon nanotubes functionalized with carboxyl groups (SWNT-COOH) having various concentrations of CNTs. The best photocatalytic performance was obtained for sample containing TiO2:N and 2.5 wt.% SWNTs-COOH, when approx. 85% of dye removal was achieved after 300 min. of UV irradiation. The reaction kinetics of RhB aqueous solutions containing TiO2:N/CNT mixtures followed a complex first-order kinetic model. The TiO2:N/CNTs catalyst induced higher photodegradation efficiency of RhB than TiO2:N due to the presence of CNTs, which act as adsorbent and dispersing agent and capture the photogenerated electrons of TiO2:N hindering the electron–hole recombination. 相似文献
30.
Ioana Moleavin Constanta Ibanescu Anca Hodorog-Rusu Ecaterina Peptu Florica Doroftei Nicolae Hurduc 《Central European Journal of Chemistry》2011,9(6):1117-1125
Amphiphilic macromolecular micelles are advantageous for drug delivery applications due to the decrease of side-effects, ease
of screening drugs against degradation, long-term stability, targeted delivery and control of the amount of the released drug.
A series of amphiphilic azo-polymers having a flexible or rigid main-chain were synthesized and characterized. The presence
of chlorobenzyl side-groups allowed both the easy bonding of photo-sensitive or hydrophilic groups and good control of the
degree of substitution. The chemical structure was confirmed by 1H-NMR. The critical concentration of aggregation (CCA) was calculated using the fluorescence emission spectrum of pyrene.
The interest was focused on a preliminary study concerning the disaggregation capacity of micelles under UV irradiation. The
presence of micellar aggregates was confirmed by DLS and SEM and different organization of the amphiphilic polymers was evidenced
depending on polymers concentration and polymers structure. In low polymer concentrations in water predominantly globular
aggregates were formed. The increase in concentration increased the polydispersity index due to the fusion of micelles and
formation of associates of globular aggregates, inter-micellar associates (clusters) and vesicles.
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